Tag Archives: Credulity

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New study: the early Earth’s atmosphere contained oxygen

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Here’s a new paper published in the prestigious peer-reviewed science journal Nature, entitled “The oxidation state of Hadean magmas and implications for early Earth’s atmosphere”.

Evolution News explains what the paper is about.

Excerpt:

A recent Nature publication reports a new technique for measuring the oxygen levels in Earth’s atmosphere some 4.4 billion years ago. The authors found that by studying cerium oxidation states in zircon, a compound formed from volcanic magma, they could ascertain the oxidation levels in the early earth. Their findings suggest that the early Earth’s oxygen levels were very close to current levels.

[…]Miller and Urey conducted experiments to show that under certain atmospheric conditions and with the right kind of electrical charge, several amino acids could form from inorganic compounds such as methane, ammonia, and water. Several experiments have been done using various inorganic starting materials, all yielding a few amino acids; however, one key aspect of all of these experiments was the lack of oxygen.

If the atmosphere has oxygen (or other oxidants) in it, then it is an oxidizing atmosphere. If the atmosphere lacks oxygen, then it is either inert or a reducing atmosphere. Think of a metal that has been left outside, maybe a piece of iron. That metal will eventually rust. Rusting is the result of the metal being oxidized. With organic reactions, such as the ones that produce amino acids, it is very important that no oxygen be present, or it will quench the reaction. Scientists, therefore, concluded that the early Earth must have been a reducing environment when life first formed (or the building blocks of life first formed) because that was the best environment for producing amino acids. The atmosphere eventually accumulated oxygen, but life did not form in an oxidative environment.

The problem with this hypothesis is that it is based on the assumption that organic life must have formed from inorganic materials. That is why the early Earth must have been a reducing atmosphere. Research has been accumulating for more than thirty years, however, suggesting that the early Earth likely did have oxygen present.

[…]This brings us back to that Nature letter, which offers another reason to question the reducing environment of the early Earth. The authors looked at the cerium oxidation levels within zircon. Zircon is a hard rock that forms from the solidification of magma. Several studies have been done with zircon because of its age and durability. (See here for a report on using zircon to determine when oceans and land were present on Earth.) Cerium (Ce) is an element that can be found in early Earth zircon. The ratio of cerium’s +3 and +4 oxidation states indicates the environmental conditions at the time the cerium was trapped in the zircon. Specifically, cerium’s oxidation ratio is related to the amount of oxygen in the atmosphere. The authors created cerium-infused zircon in the lab at various oxidative ratios to make a calibration curve to which they could then compare the early Earth samples.

Their findings not only showed that oxygen was present in the early Earth atmosphere, something that has been shown in other studies, but that oxygen was present as early as 4.4 billion years ago. This takes the window of time available for life to have begun, by an origin-of-life scenario like the RNA-first world, and reduces it to an incredibly short amount of time. Several factors need to coincide in order for nucleotides or amino acids to form from purely naturalistic circumstances (chance and chemistry). The specific conditions required already made purely naturalist origin-of-life scenarios highly unlikely. Drastically reducing the amount of time available, adding that to the other conditions needing to be fulfilled, makes the RNA world hypothesis or a Miller-Urey-like synthesis of amino acids simply impossible.

So here’s where we stand. If you are a materialist, then you need a reducing environment on the early Earth in order to get organic building blocks (amino acids) from inorganic materials. However, the production of these organic building blocks (amino acids) requires that the early Earth atmosphere be oxygen-free. And the problem with this new research, which confirms previous research, is that the early Earth contained huge amounts of oxygen – the same amount of oxygen as we have today. This is lethal to naturalistic scenarios for creating the building blocks of life on the Earth’s surface.

Other problems

If you would like to read a helpful overview of the problems with a naturalistic scenario for the origin of life, check out this article by Casey Luskin.

Excerpt:

The “origin of life” (OOL) is best described as the chemical and physical processes that brought into existence the first self-replicating molecule. It differs from the “evolution of life” because Darwinian evolution employs mutation and natural selection to change organisms, which requires reproduction. Since there was no reproduction before the first life, no “mutation – selection” mechanism was operating to build complexity. Hence, OOL theories cannot rely upon natural selection to increase complexity and must create the first life using only the laws of chemistry and physics.

There are so many problems with purely natural explanations for the chemical origin of life on earth that many scientists have already abandoned all hopes that life had a natural origin on earth. Skeptical scientists include Francis Crick (solved the 3-dimensional structure of DNA1) and Fred Hoyle (famous British cosmologist and mathematician), who, in an attempt to retain their atheistic worldviews, then propose outrageously untestable cosmological models or easily falsifiable extra-terrestrial-origin-of-life / panspermia scenarios2 which still do not account for the natural origin of life. So drastic is the evidence that Scientific American editor John Horgan wrote, “[i]f I were a creationist, I would cease attacking the theory of evolution … and focus instead on the origin of life. This is by far the weakest strut of the chassis of modern biology.”3

The article goes over the standard problems with naturalistic scenarios of the origin of life: wrong atmosphere, harmful UV radiation, interfering cross-reactions, molecular oxygen, meteorite impacts, chirality, etc.

Charles Thaxton explains the origin of life

Here’s a helpful little video on the problem from origin of life chemist Charles Thaxton, who authored “The Mystery of Life’s Origin” with Walter Bradley and Roger Olsen.

There’s another video like this one featuring Dean Kenyon, and you can get the video clips online here. I really wish someone would post it online. I have the video and ripped it from my VHS tape, so maybe I should do it! It’s a great interview. Both of these videos (Thaxton, Kenyon) are highly recommended for intermediate and advanced Christians. For beginners, I would recommed “Unlocking the Mystery of Life”, which you can watch for free right here:

If you are looking for a hot issue to put some time into, then this is a good place to start. And note that this problem of the building blocks of life is logically prior to the problem of forming functional sequences of amino acids (e.g. – proteins), which people like Stephen C. Meyer debate about. In debates on the origin of life, ID people usually just assume that the amino acids exist, and then get on with discussing the problem of generating sequences of amino acids and base pairs into sequences that exhibit specified complexity. But as you see from the research, it’s an unwarranted assumption – those building blocks are not a given, and the naturalist has to account for them.

Polemics

Can naturalism account for the origin of the 20 amino acids in living systems?

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The origin of life

There are two problems related to the origin of the first living cell, on atheism:

  1. The problem of getting the building blocks needed to create life – i.e. the amino acids
  2. The problem of creating the functional sequences of amino acids and proteins that can support the minimal operations of a simple living cell

Normally, I concede the first problem and grant the atheist all the building blocks he needs. This is because step 2 is impossible. There is no way, on atheism, to form the sequences of amino acids that will fold up into proteins, and then to form the sequences of proteins that can be used to form everything else in the cell, including the DNA itself. But that’s tomorrow’s topic.

Today, let’s take a look at the problems with step 1.

The problem of getting the building blocks of life

Now you may have heard that some scientists managed to spark some gasses to generate most of the 20 amino acids found in living systems. These experiments are called the “Miller-Urey” experiments.

The IDEA center has a nice summary of origin-of-life research that explains a few of the main problems with step 1.

Miler and Urey used the wrong gasses:

Miller’s experiment requires a reducing methane and ammonia atmosphere,11, 12 however geochemical evidence says the atmosphere was hydrogen, water, and carbon dioxide (non-reducing).15, 16 The only amino acid produced in a such an atmosphere is glycine (and only when the hydrogen content is unreasonably high), and could not form the necessary building blocks of life.11

Miller and Urey didn’t account for UV of molecular instability:

Not only would UV radiation destroy any molecules that were made, but their own short lifespans would also greatly limit their numbers. For example, at 100ºC (boiling point of water), the half lives of the nucleic acids Adenine and Guanine are 1 year, uracil is 12 years, and cytozine is 19 days20 (nucleic acids and other important proteins such as chlorophyll and hemoglobin have never been synthesized in origin-of-life type experiments19).

Miller and Urey didn’t account for molecular oxygen:

We all have know ozone in the upper atmosphere protects life from harmful UV radiation. However, ozone is composed of oxygen which is the very gas that Stanley Miller-type experiments avoided, for it prevents the synthesis of organic molecules like the ones obtained from the experiments! Pre-biotic synthesis is in a “damned if you do, damned if you don’t” scenario. The chemistry does not work if there is oxygen because the atmosphere would be non-reducing, but if there is no UV-light-blocking oxygen (i.e. ozone – O3) in the atmosphere, the amino acids would be quickly destroyed by extremely high amounts of UV light (which would have been 100 times stronger than today on the early earth).20, 21, 22 This radiation could destroy methane within a few tens of years,23 and atmospheric ammonia within 30,000 years.15

And there were three other problems too:

At best the processes would likely create a dilute “thin soup,”24 destroyed by meteorite impacts every 10 million years.20, 25 This severely limits the time available to create pre-biotic chemicals and allow for the OOL.

Chemically speaking, life uses only “left-handed” (“L”) amino acids and “right-handed” (“R)” genetic molecules. This is called “chirality,” and any account of the origin of life must somehow explain the origin of chirality. Nearly all chemical reactions produce “racemic” mixtures–mixtures with products that are 50% L and 50% R.

Two more problems are not mentioned in the article. A non-peptide bond anywhere in the chain will ruin the chain. You need around 200 amino acids to make a protein. If any of the bonds is not a peptide bond, the chain will not work in a living system. Additionally, the article does not mention the need for the experimenter to intervene in order to prevent interfering cross-reactions that would prevent the amino acids from forming.

Usually when you hear the origin of life debated, they sort of skirt about the problem of where the amino acids come from, but there is no reason not to make that an issue. The naturalist has to explain how the first living cell could come about naturalistically.

Further study

One of my favorite resources on the origin of life is this interview from the University of California with former atheist and origin of life researcher Dean Kenyon. Kenyon, a professor of Biology at San Francisco State University, wrote the textbook on “chemical evolution”, which is the view that chemicals can arrange themselves in order to create the first living cell, without intervention.

This interview from the University of California with another origin of life researcher, Charles Thaxton, is also one of my favorites.

You’ll need Quicktime to see the videos, or buy the videos from ARN. (Kenyon, Thaxton) I have both of them – they rock!

News

Is the taxpayer-funded scientific bureaucracy self-correcting?

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Consider this post from Evolution News which talks about a paper in the prestigious pro-naturalism journal Science that is drawing a lot of criticisms. (H/T Melissa, Jonathan)

Excerpt:

Last December we reported on a controversial paper published in Science which claimed to have discovered bacteria that feed on arsenic instead of phosphorous. According to NASA, this research promised to provide “an astrobiology finding that will impact the search for evidence of extraterrestrial life.” At that time the media reported things like:

  • scientists discovered “a bacteria whose DNA is completely alien to what we know today” (Wired)
  • the “bacteria is made of arsenic” (Wired)
  • the bacteria is “capable of using arsenic to build its DNA, RNA, proteins, and cell membranes” (Gizmodo)
  • the paper had reported “arsenic-based life” which is “very alien in terms of how it’s put together” and “NASA has, in a very real sense, discovered a form of alien life” (io9)
  • “you can potentially cross phosphorus off the list of elements required for life” (Nature)

But soon after the original Science paper was published, credible scientists began critiquing the paper’s claims. In the June 3, 2011 issue of Science, several of those scientists have published comments critiquing the original paper. Many of their criticisms focus on the claim that the original paper did not establish or rule out the possibility that the bacteria are not still living off of phosphorous.

So you have a paper being published that everyone is excited about because it helps the naturalists to close gaps in their worldview. But was it good science? The Evolution News piece goes on to list the criticisms of the paper.

And here is the result:

Of course the authors of the original paper, including lead-author Felisa Wolf-Simon, co-authored a reply to the criticisms which should also be read. But critics remain unconvinced. Nature news recently quoted Barry Rosen of Florida International University stating, “I have not found anybody outside of [Wolfe-Simon’s] laboratory who supports the work.” Likewise, Rosie Redfield observes:

“With so many mistakes pointed out, there should be at least some where the authors say, ‘you’re right, we should have done that but we didn’t’,” Redfield says. “This as an entirely a ‘we were right’ response, and that’s a bad sign in science.”

Despite the high levels of skepticism of claims of arsenophilic bacteria, Nature reports that few scientists have taken the initiative to attempt to experimentally reproduce the claims made in the original paper:

However, most labs seem too busy to spend time replicating work that they feel is fundamentally flawed and is not likely to be published in high-impact journals. So principal investigators are reluctant to spend their resources, and their students’ time, replicating the work. “If you extended the results to show there is no detectable arsenic, where could you publish that?” asks Simon Silver of the University of Illinois at Chicago, who critiqued the work in FEMS Microbiology Letters in January and on 24 May at the annual meeting of the American Society for Microbiology in New Orleans. “How could the young person who was asked to do that work ever get a job?” Refuting another scientist’s work also takes time that scientists could be spending on their own research. For instance, Helmann says he is installing a highly sensitive mass spectrometer that can measure trace amounts of elements. But, he says, “I’ve got my own science to do.”

Such admissions do not bode well for those who blindly believe in the perfectly objective, self-correcting nature of science. In this case, it seems safe to experimentally critique these claims since so many respected scientists have already expressed vocal skepticism. Yet experiments are apparently not yet forthcoming. What about areas of science where scientists are not able to express their dissent freely? For example, who would take time to experimentally critique claims that are central to neo-Darwinian theory, especially if it’s dangerous to one’s career? One hopes that science will become more self-correcting when it comes to claims made in support of materialism.

In light of what we now know about global warming research, shouldn’t we be a little more welcoming of whistleblowers and critics? Shouldn’t we be a little more careful about hastily approving research that agrees with the religion of naturalism, instead of checking it over thoroughly to make sure that it really is good science?