Tag Archives: Oxygen

Study: the early Earth’s atmosphere contained oxygen

Apologetics and the progress of science
Apologetics and the progress of science

Here’s a paper published in the prestigious peer-reviewed science journal Nature, entitled “The oxidation state of Hadean magmas and implications for early Earth’s atmosphere”. This paper is significant because it undermines naturalistic scenarios for the origin of life.

Evolution News explains what the paper is about.


A recent Nature publication reports a new technique for measuring the oxygen levels in Earth’s atmosphere some 4.4 billion years ago. The authors found that by studying cerium oxidation states in zircon, a compound formed from volcanic magma, they could ascertain the oxidation levels in the early earth. Their findings suggest that the early Earth’s oxygen levels were very close to current levels.

[…]Miller and Urey conducted experiments to show that under certain atmospheric conditions and with the right kind of electrical charge, several amino acids could form from inorganic compounds such as methane, ammonia, and water. Several experiments have been done using various inorganic starting materials, all yielding a few amino acids; however, one key aspect of all of these experiments was the lack of oxygen.

If the atmosphere has oxygen (or other oxidants) in it, then it is an oxidizing atmosphere. If the atmosphere lacks oxygen, then it is either inert or a reducing atmosphere. Think of a metal that has been left outside, maybe a piece of iron. That metal will eventually rust. Rusting is the result of the metal being oxidized. With organic reactions, such as the ones that produce amino acids, it is very important that no oxygen be present, or it will quench the reaction. Scientists, therefore, concluded that the early Earth must have been a reducing environment when life first formed (or the building blocks of life first formed) because that was the best environment for producing amino acids. The atmosphere eventually accumulated oxygen, but life did not form in an oxidative environment.

The problem with this hypothesis is that it is based on the assumption that organic life must have formed from inorganic materials. That is why the early Earth must have been a reducing atmosphere. Research has been accumulating for more than thirty years, however, suggesting that the early Earth likely did have oxygen present.

[…]Their findings not only showed that oxygen was present in the early Earth atmosphere, something that has been shown in other studies, but that oxygen was present as early as 4.4 billion years ago. This takes the window of time available for life to have begun, by an origin-of-life scenario like the RNA-first world, and reduces it to an incredibly short amount of time. Several factors need to coincide in order for nucleotides or amino acids to form from purely naturalistic circumstances (chance and chemistry). The specific conditions required already made purely naturalist origin-of-life scenarios highly unlikely. Drastically reducing the amount of time available, adding that to the other conditions needing to be fulfilled, makes the RNA world hypothesis or a Miller-Urey-like synthesis of amino acids simply impossible.

So here’s where we stand. If you are a materialist, then you need a reducing environment on the early Earth in order to get organic building blocks (amino acids) from inorganic materials. However, the production of these organic building blocks (amino acids) requires that the early Earth atmosphere be oxygen-free. And the problem with this new research, which confirms previous research, is that the early Earth contained huge amounts of oxygen – the same amount of oxygen as we have today. This is lethal to naturalistic scenarios for creating the building blocks of life on the Earth’s surface.

Other problems

If you would like to read a helpful overview of the problems with a naturalistic scenario for the origin of life, check out this article by Casey Luskin.


The “origin of life” (OOL) is best described as the chemical and physical processes that brought into existence the first self-replicating molecule. It differs from the “evolution of life” because Darwinian evolution employs mutation and natural selection to change organisms, which requires reproduction. Since there was no reproduction before the first life, no “mutation – selection” mechanism was operating to build complexity. Hence, OOL theories cannot rely upon natural selection to increase complexity and must create the first life using only the laws of chemistry and physics.

There are so many problems with purely natural explanations for the chemical origin of life on earth that many scientists have already abandoned all hopes that life had a natural origin on earth. Skeptical scientists include Francis Crick (solved the 3-dimensional structure of DNA) and Fred Hoyle (famous British cosmologist and mathematician), who, in an attempt to retain their atheistic worldviews, then propose outrageously untestable cosmological models or easily falsifiable extra-terrestrial-origin-of-life / panspermia scenarios which still do not account for the natural origin of life. So drastic is the evidence that Scientific American editor John Horgan wrote, “[i]f I were a creationist, I would cease attacking the theory of evolution … and focus instead on the origin of life. This is by far the weakest strut of the chassis of modern biology.”3

The article goes over the standard problems with naturalistic scenarios of the origin of life: wrong atmosphere, harmful UV radiation, interfering cross-reactions, oxygen levels, meteorite impacts, chirality, etc.

Most people who are talking about intelligent design at the origin of life talk about the information problem – how do you get the amino acids to form proteins and how do you get nucleotide bases to code for amino acids? But the starting point for solving the sequencing problem is the construction of the amino acids – there has to be a plausible naturalistic scenario to form them.

The formation of the elements required for complex embodied life is fine-tuned

Apologetics and the progress of science
Apologetics and the progress of science

Some atheists who don’t understand the fine-tuning argument like to assert that the constants and quantities that are fine-tuned to allow for the existence of complex, embodied life can be changed arbitrarily, and life would still exist as it does now. They say that maybe we would have a ridges in our foreheads like Klingons, or maybe we would have longer ears like Vulcans or maybe green skin like Orions. The evidential support for this view seems to be grounded in Star Trek TV shows, not peer-reviewed evidence. Are atheists right to ground their rejection of a cosmic Designer in science fiction television shows? What does the peer-reviewed research say?

The fine-tuning argument

First, let’s review the structure of the fine-tuning argument.

The argument goes like this:

  1. The fine-tuning of the universe to support life is either due to law, chance or design
  2. It is not due to law or chance
  3. Therefore, the fine-tuning is due to design

Although each permutation of values for the constants and quantities is equally improbable, the vast majority of the permutations will not permit life.

Let’s review:

  • Life has certain minimal requirements; long-term stable source of energy, a large number of different chemical elements, an element that can serve as a hub for joining together other elements into compounds, a universal solvent, etc.
  • In order to meet these minimal requirements, the physical constants, (such as the gravitational constant), and the ratios between physical constants, need to be withing a narrow range of values in order to support the minimal requirements for life of any kind.
  • Slight changes to any of the physical constants, or to the ratios between the constants, will result in a universe inhospitable to life.
  • The range of possible values spans 70 orders of magnitude.
  • The constants are selected by whoever creates the universe. They are not determined by physical laws. And the extreme probabilities involved required put the fine-tuning beyond the reach of chance.
  • Although each individual selection of constants and ratios is as unlikely as any other selection, the vast majority of these possibilities do not support the minimal requirements of life of any kind. (In the same way as any hand of 5 cards that is dealt is as likely as any other, but you are overwhelmingly likely NOT to get a royal flush. In our case, a royal flush is a life-permitting universe).

Now let’s see a specific example: carbon and oxygen formation.

Carbon is that element that can serve as a hub for larger molecules, and oxygen is also a vital element, since it is a component of water, which is required for life (universal solvent). Both are required for complex life of any imaginable kind.

Now for the study.

Here is an article on Science Daily about the fine-tuning argument.

It says:

Life as we know it is based upon the elements of carbon and oxygen. Now a team of physicists, including one from North Carolina State University, is looking at the conditions necessary to the formation of those two elements in the universe. They’ve found that when it comes to supporting life, the universe leaves very little margin for error.

Both carbon and oxygen are produced when helium burns inside of giant red stars. Carbon-12, an essential element we’re all made of, can only form when three alpha particles, or helium-4 nuclei, combine in a very specific way. The key to formation is an excited state of carbon-12 known as the Hoyle state, and it has a very specific energy — measured at 379 keV (or 379,000 electron volts) above the energy of three alpha particles. Oxygen is produced by the combination of another alpha particle and carbon.

NC State physicist Dean Lee and German colleagues Evgeny Epelbaum, Hermann Krebs, Timo Laehde and Ulf-G. Meissner had previously confirmed the existence and structure of the Hoyle state with a numerical lattice that allowed the researchers to simulate how protons and neutrons interact. These protons and neutrons are made up of elementary particles called quarks. The light quark mass is one of the fundamental parameters of nature, and this mass affects particles’ energies.

In new lattice calculations done at the Juelich Supercomputer Centre the physicists found that just a slight variation in the light quark mass will change the energy of the Hoyle state, and this in turn would affect the production of carbon and oxygen in such a way that life as we know it wouldn’t exist.

[…]The researchers’ findings appear in Physical Review Letters.

There are many, many other examples of fine-tuning of the constants and quantities to permit complex, embodied life. And, as we’ll see below, this evidence is admitted by atheists.

Atheists agree: the fine-tuning is a fact

Let me give you a citation from the best one of all, Martin Rees. Martin Rees is an atheist and a qualified astronomer. He wrote a book called “Just Six Numbers: The Deep Forces That Shape The Universe”, (Basic Books: 2001). In it, he discusses 6 numbers that need to be fine-tuned in order to have a life-permitting universe.

In chapter 1, Rees writes:

Mathematical laws underpin the fabric of our universe — not just atoms, but galaxies, stars and people. The properties of atoms — their sizes and masses, how many different kinds there are, and the forces linking them together — determine the chemistry of our everyday world. The very existence of atoms depends on forces and particles deep inside them. The objects that astronomers study — planets, stars and galaxies — are controlled by the force of gravity. And everything takes place in the arena of an expanding universe, whose properties were imprinted into it at the time of the initial Big Bang.

[…]This book describes six numbers that now seem especially significant.

[…]Perhaps there are some connections between these numbers. At the moment, however, we cannot predict any one of them from the values of the others.

[…]These six numbers constitute a ‘recipe’ for a universe. Moreover, the outcome is sensitive to their values: if any one of them were to be ‘untuned’, there would be no stars and no life. Is this tuning just a brute fact, a coincidence? Or is it the providence of a benign Creator?

There are some atheists who deny the fine-tuning, but these atheists are in firm opposition to the progress of science. The more science has progressed, the more constants, ratios and quantities we have discovered that need to be fine-tuned. Science is going in a theistic direction. Next, let’s see how atheists try to account for the fine-tuning.

Atheistic responses to the fine-tuning evidence

There are two common responses among atheists to this argument.

The first is to speculate that there are actually an infinite number of other universes that are not fine-tuned, (i.e. – the gambler’s fallacy). All these other universes don’t support life. We just happen to be in the one universe is fine-tuned for life. The problem is that there is no way of directly observing these other universes and no independent evidence that they exist.

Here is an excerpt from an article in Discover magazine, (which is hostile to theism and Christianity).

Short of invoking a benevolent creator, many physicists see only one possible explanation: Our universe may be but one of perhaps infinitely many universes in an inconceivably vast multiverse. Most of those universes are barren, but some, like ours, have conditions suitable for life.

The idea is controversial. Critics say it doesn’t even qualify as a scientific theory because the existence of other universes cannot be proved or disproved. Advocates argue that, like it or not, the multiverse may well be the only viable non­religious explanation for what is often called the “fine-tuning problem”—the baffling observation that the laws of the universe seem custom-tailored to favor the emergence of life.

The second response by atheists is that the human observers that exist today, 14 billion years after the universe was created out of nothing, actually caused the fine-tuning by going back in time and causing the universe to be fine-tuned. This solution would mean that although humans did not exist at the time the of the big bang, they are going to be able to reach back in time at some point in the future and manually fine-tune the universe.

Here is an excerpt from and article in the New Scientist, (which is hostile to theism and Christianity).

…maybe we should approach cosmic fine-tuning not as a problem but as a clue. Perhaps it is evidence that we somehow endow the universe with certain features by the mere act of observation… observers are creating the universe and its entire history right now. If we in some sense create the universe, it is not surprising that the universe is well suited to us.

So, there are two choices for atheists. Either an infinite number of unobservable universes that are not fine-tuned, or humans go back in time at some future point and fine-tune the beginning of the universe, billions of years in the past. I think I will prefer the design explanation to those alternatives.

Positive arguments for Christian theism

Can naturalism account for the origin of the 20 amino acids in living systems?

Do the Miller-Urey experiments simulate the early Earth?
Do the Miller-Urey experiments simulate the early Earth?

The origin of life

There are two problems related to the origin of the first living cell, on naturalism:

  1. The problem of getting the building blocks needed to create life – i.e. the amino acids
  2. The problem of creating the functional sequences of amino acids and proteins that can support the minimal operations of a simple living cell

Normally, I concede the first problem and grant the naturalist all the building blocks he needs. This is because step 2 is impossible. There is no way, on naturalism, to form the sequences of amino acids that will fold up into proteins, and then to form the sequences of proteins that can be used to form everything else in the cell, including the DNA itself. But that’s a topic for a separate post.

Today, let’s take a look at the problems with step 1.

The problem of getting the building blocks of life

Now you may have heard that some scientists managed to spark some gasses to generate most of the 20 amino acids found in living systems. These experiments are called the “Miller-Urey” experiments.

The IDEA center has a nice summary of origin-of-life research that explains a few of the main problems with step 1.

Miler and Urey used the wrong gasses:

Miller’s experiment requires a reducing methane and ammonia atmosphere,11, 12 however geochemical evidence says the atmosphere was hydrogen, water, and carbon dioxide (non-reducing).15, 16 The only amino acid produced in a such an atmosphere is glycine (and only when the hydrogen content is unreasonably high), and could not form the necessary building blocks of life.11

Miller and Urey didn’t account for UV of molecular instability:

Not only would UV radiation destroy any molecules that were made, but their own short lifespans would also greatly limit their numbers. For example, at 100ºC (boiling point of water), the half lives of the nucleic acids Adenine and Guanine are 1 year, uracil is 12 years, and cytozine is 19 days20 (nucleic acids and other important proteins such as chlorophyll and hemoglobin have never been synthesized in origin-of-life type experiments19).

Miller and Urey didn’t account for molecular oxygen:

We all have know ozone in the upper atmosphere protects life from harmful UV radiation. However, ozone is composed of oxygen which is the very gas that Stanley Miller-type experiments avoided, for it prevents the synthesis of organic molecules like the ones obtained from the experiments! Pre-biotic synthesis is in a “damned if you do, damned if you don’t” scenario. The chemistry does not work if there is oxygen because the atmosphere would be non-reducing, but if there is no UV-light-blocking oxygen (i.e. ozone – O3) in the atmosphere, the amino acids would be quickly destroyed by extremely high amounts of UV light (which would have been 100 times stronger than today on the early earth).20, 21, 22 This radiation could destroy methane within a few tens of years,23 and atmospheric ammonia within 30,000 years.15

And there were three other problems too:

At best the processes would likely create a dilute “thin soup,”24 destroyed by meteorite impacts every 10 million years.20, 25 This severely limits the time available to create pre-biotic chemicals and allow for the OOL.

Chemically speaking, life uses only “left-handed” (“L”) amino acids and “right-handed” (“R)” genetic molecules. This is called “chirality,” and any account of the origin of life must somehow explain the origin of chirality. Nearly all chemical reactions produce “racemic” mixtures–mixtures with products that are 50% L and 50% R.

Two more problems are not mentioned in the article. A non-peptide bond anywhere in the chain will ruin the chain. You need around 200 amino acids to make a protein. If any of the bonds is not a peptide bond, the chain will not work in a living system. Additionally, the article does not mention the need for the experimenter to intervene in order to prevent interfering cross-reactions that would prevent the amino acids from forming.

Usually when you hear the origin of life debated, they sort of skirt about the problem of where the amino acids come from, but there is no reason not to make that an issue. The naturalist has to explain how the first living cell could come about naturalistically.

Positive arguments for Christian theism